Late Stage Capitalism
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Gunpowder is a bitch. I don't even know where to find potassium nitrate off the top of my head. You can get sulphur from hot springs and charcoal is simple. From experience, in a lab environment, getting the ratios for a useful explosion is a hard, even when you know what the possibilities are. Unless you have this memorized, that will be a 5 to 10 year adventure.
Thankfully, this is an easy problem to solve. If you're planning a time trip, just research the locations of potassium nitrate deposits before you go.
Now I'm imagining a movie where someone tries this. Except, as you alluded, the only way to really do this would be to completely change indigenous society. As the movie goes on, it becomes clear the protagonist is just doing colonialism all over again. Sure, they can say, "it's for their own good though!" The cry of every Christian missionary.
Smart. They would probably think your a prophet if you could do things like that. I think the hardest part is convincing them into at least a semi industrialist type mindset.
iirc, we were pretty dependent getting nitrates for gunpowder from urine and bat guano until we were able to start synthesizing it.
Guncotton might just be easier, and far more effective.